The thickness dependence of the interband transition photovoltaic voltage and the short-circuit photocurrent in zinc sulphide photocells
Identifieur interne : 001673 ( France/Analysis ); précédent : 001672; suivant : 001674The thickness dependence of the interband transition photovoltaic voltage and the short-circuit photocurrent in zinc sulphide photocells
Auteurs : M. Arsalane [France] ; A. J. Tosser [France]Source :
- Thin Solid Films [ 0040-6090 ] ; 1977.
Abstract
Using previously proposed band models calculations are given to determine the open-circuit photovoltages Vpho and the short-circuit currents Iphsc that are induced by light with an energy of more than 3.66 eV in Al/ZnS/Au photocells. The assumption that the interband photo-transitions and the electronic photo-emission from coulombic centres are separate may be used for sulphide thicknesses of more than 200 Å; the variations of Vpho and Iphsc with light intensity are only attributed to the interband transition. For sulphide thicknesses less than 200 Å the conduction band is perturbed twice because of the critical layer; photo-emission from the coulombic centres is enhanced; experimental thickness dependences are proposed that deviate markedly from the theoretical laws.
Url:
DOI: 10.1016/0040-6090(77)90419-9
Affiliations:
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ISTEX:C5995C0259F97148C443977DEE01EBDE65F4DDF0Le document en format XML
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<front><div type="abstract" xml:lang="en">Using previously proposed band models calculations are given to determine the open-circuit photovoltages Vpho and the short-circuit currents Iphsc that are induced by light with an energy of more than 3.66 eV in Al/ZnS/Au photocells. The assumption that the interband photo-transitions and the electronic photo-emission from coulombic centres are separate may be used for sulphide thicknesses of more than 200 Å; the variations of Vpho and Iphsc with light intensity are only attributed to the interband transition. For sulphide thicknesses less than 200 Å the conduction band is perturbed twice because of the critical layer; photo-emission from the coulombic centres is enhanced; experimental thickness dependences are proposed that deviate markedly from the theoretical laws.</div>
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